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The article considers problems of research of museum art porcelain and faience of the XIX – the beginning of the XX century in the process of carrying out fine art expertise and also reveals the main criteria of Museum attribution. An important part of the examination methodology of thin-ceramic products is the development of special methods for their study in the conditions of modern laboratories on the latest-generation devices. The results presented in the article can contribute to the practical application of the proposed methods in conducting art criticism of art porcelain and faience in the museum research and restoration work.